380356-22-9Relevant academic research and scientific papers
Asymmetric Michael additions of a chiral phosphite to nitroalkenes and knoevenagel acceptors
Enders, Dieter,Tedeschi, Livio,Foerster, Dominik
, p. 1447 - 1460 (2007/10/03)
The diastereoselective Michael addition of an enantiopure phosphite to nitroalkenes and α,β-unsaturated malonates is described. High asymmetric inductions were obtained using a readily available TADDOL auxiliary. Racemization-free cleavage of the auxiliar
Asymmetric synthesis of β-phosphono malonates via Fe2O3-mediated phospha-Michael addition to Knoevenagel acceptors
Tedeschi, Livio,Enders, Dieter
, p. 3515 - 3517 (2007/10/03)
(matrix presented) The first asymmetric P-C bond formation under heterogeneous conditions was achieved via a Fe2O3-mediated conjugate addition of a chiral phosphite to alkylidene malonates. The easy cleavage of the chiral auxiliary f
