380360-34-9Relevant academic research and scientific papers
Preparation, structure, and property of organic isothiocyanide-Fe(II) complexes, trans-[FeH(NCSR)(dppe)2][X] (dppe = Ph2PCH2CH2PPh2; R = Me, Et, Pr, i-Pr, CH2CH=CH2, CH2CCH; X = I, Br, CF3SO3, BF4)
Lee, Ji Hwa,Yoo, Beom-Sang,Lee, Soon W.
, p. 75 - 82 (2008/10/08)
The compound trans-[FeH(Cl)(dppe)2] (1) reacted with KSCN to give trans-[FeH(NCS)(dppe)2] (2), which underwent electrophilic attack by alkyl iodides or alkyl bromides (RX) to give organic isothiocyanide-Fe(II) complexes of the type trans-[FeH(NCSR)(dppe)2]X {X = I: R = Me (3), Et (4), Pr (5), CH2CH=CH2 (6), i-Pr (7); X = Br: R = Pr (8), CH2CH=CH2 (9), CH2C≡CH (10)}. Compound 2 also reacted with strong electrohphiles, MeSO3CF3 and Me3O·BF4, to give trans-[FeH(NCSMe)(dppe)2][SO3CF3] (11) and trans-[FeH(NCSMe)(dppe)2][BF4] (12), respectively. Compounds 2 and 11 were characterized structurally by X-ray diffraction, in which the hydride ligand appears to be involved in the dihydrogen bonding, M-H···H-C. 2001 Elsevier Science B.V. All rights reserved.
