38041-07-5Relevant academic research and scientific papers
PHOTOLYSIS AND THERMOLYSIS OF 1,2,3-TRISILACYCLOPENTENE. REGIOSPECIFIC AND NON-REGIOSPECIFIC SILYLENE EXTRUSION.
Nakadaira, Yasuhiro,Sato, Ryuji,Kida, Nobutsugu,Sakurai, Hideki
, p. 393 - 396 (2007/10/02)
1,2,3-Trisilacyclopent-4-ene generates silylene to give 1,2-disilacyclobut-3-ene on both photolysis and thermolysis.The silylene arises from either the central or the terminal silicon atom of the ring depending on the nature of substituents on the central
Photolysis of Organopolysilanes. Photochemical Behavior of Phenylethynyldisilanes
Ishikawa, Mitsuo,Sugisawa, Hiroshi,Fuchikami, Takamasa,Kumada, Makoto,Yamabe, Tokio,et al.
, p. 2872 - 2878 (2007/10/02)
The photolysis of phenylethynylpentamethyldisilane (1) afforded 1,1-dimethyl-2-phenyl-3-trimethylsilyl-1-silacyclopropene (8) and 1,1-dimethyl-3-phenyl-3-trimethylsilyl-1-silapropadiene.The absorption and emission spectra of 1 were measured at 300 and 77
