38049-83-1Relevant academic research and scientific papers
Tri-n-butylphosphine-Catalyzed Phosphonoethylation Reactions of Hydrophosphoryl Compounds
Il’in,Antonova,Khusainova,Galkin
, p. 2207 - 2211 (2019)
An efficient method for the synthesis of 1,2-bisphosphoryl compounds based on the addition of hydrophosphoryl derivatives to O,O-diethyl vinylphosphonate was developed. The reaction proceeds in mild conditions under catalysis with tri-n-butylphosphine and leads to the formation of the corresponding target products with high yield.
Air-induced anti-Markovnikov addition of secondary phosphine oxides and H-phosphinates to alkenes
Hirai, Takayoshi,Han, Li-Biao
, p. 53 - 55 (2007/10/03)
(Chemical Equation Presented) Air (oxygen) induces the addition of secondary phosphine oxides and H-phosphinates to alkenes to selectively produce the corresponding anti-Markovnikov adducts in good to high yields. Mechanistic studies show that the addition probably proceeds via a radical chain mechanism.
Microwave-assisted regioselective addition of P(O)-H bonds to alkenes without added solvent or catalyst
Stockland Jr., Robert A.,Taylor, Ross I.,Thompson, Laura E.,Patel, Priti B.
, p. 851 - 853 (2007/10/03)
(Chemical Equation Presented) The addition of P(O)-H bonds to alkenes has been accomplished using microwave irradiation in the absence of added solvent and catalyst. In addition to single addition reactions, tandem hydrophosphinylation reactions with alky
