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38050-71-4

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38050-71-4 Usage

Uses

Different sources of media describe the Uses of 38050-71-4 differently. You can refer to the following data:
1. Pro-nucleophile and co-catalyst for indium-catalyzed allylations of methyl ethers and carbohydrate derivatives. Catalyst for preparation of linear allenes from other allenes 2 Reactant for: Stereoconvergent Suzuki cross-coupling reactions 3 B-alkyl Suzuki-Miyaura cross-coupling reactions 4 Preparation of borabicyclononanyl amino acid complexes for selective treatment of malignant melanoma 5 Asymmetric synthesis of isomerically pure allenyl boranes through insertion and borotropic rearrangement.
2. 9-Methoxy-9-borabicyclo[3.3.1]nonane is a coupling reagent used in reactions like the synthesis of (-)-brevenal a polycyclic ether.
3. Pro-nucleophile and co-catalyst for indium-catalyzed allylations of methyl ethers and carbohydrate derivativesCatalyst for preparation of linear allenes from other allenesReactant for:Stereoconvergent Suzuki cross-coupling reactionsB-alkyl Suzuki-Miyaura cross-coupling reactionsPreparation of borabicyclononanyl amino acid complexes for selective treatment of malignant melanomaAsymmetric synthesis of isomerically pure allenyl boranes through insertion and borotropic rearrangement

Check Digit Verification of cas no

The CAS Registry Mumber 38050-71-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,8,0,5 and 0 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 38050-71:
(7*3)+(6*8)+(5*0)+(4*5)+(3*0)+(2*7)+(1*1)=104
104 % 10 = 4
So 38050-71-4 is a valid CAS Registry Number.
InChI:InChI=1/C9H17BO/c1-11-10-8-4-2-5-9(10)7-3-6-8/h8-9H,2-7H2,1H3

38050-71-4 Well-known Company Product Price

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  • Aldrich

  • (196223)  B-Methoxy-9-BBNsolution  1.0 M in hexanes

  • 38050-71-4

  • 196223-100ML

  • 834.21CNY

  • Detail

38050-71-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 9-METHOXY-9-BORABICYCLO[3.3.1]NONANE

1.2 Other means of identification

Product number -
Other names 9-MeO-9-BBN

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:38050-71-4 SDS

38050-71-4Relevant articles and documents

Hydroboration of carbon dioxide enabled by molecular zinc dihydrides

Chang, Kejian,Wang, Xiaoming,Xu, Xin

, p. 7324 - 7327 (2020)

Neutral molecular zinc(ii) dihydrides supported by N-heterocyclic carbene ligands bearing a pendant phosphine group were synthesized and then reacted with carbon dioxide to afford zinc diformates. The zinc dihydrides were found to be active catalysts for hydroboration of carbon dioxide under mild conditions, selectively giving boryl formate, bis(boryl)acetal, or methoxy borane compounds by changing the nature of the borane reductant.

Catalytic properties of nickel bis(phosphinite) pincer complexes in the reduction of CO2 to methanol derivatives

Chakraborty, Sumit,Patel, Yogi J.,Krause, Jeanette A.,Guan, Hairong

, p. 30 - 34 (2012)

A new nickel bis(phosphinite) pincer complex [2,6-(R2PO) 2C6H3]NiCl (LRNiCl, R = cyclopentyl) has been prepared in one pot from resorcinol, ClP(C5H 9)2, NiCl2, and 4-dimethylaminopyridine. The reaction of this pincer compound with LiAlH4 produces a nickel hydride complex, which is capable of reducing CO2 rapidly at room temperature to give a nickel formate complex. X-ray structures of two related nickel formate complexes LRNiOCHO (R = cyclopentyl and isopropyl) have shown an "in plane" conformation of the formato group with respect to the coordination plane. The stoichiometric reaction of nickel formate complexes LRNiOCHO (R = cyclopentyl, isopropyl, and tert-butyl) with catecholborane has suggested that the reaction is favored by a bulky R group. LRNiOCHO (R = tert-butyl) does not react with PhSiH3 at room temperature; however, it reacts with 9-borabicyclo[3.3.1]nonane and pinacolborane to generate a methanol derivative and a boryl formate species, respectively. The catalytic reduction of CO2 with catecholborane is more effectively catalyzed by a more sterically hindered nickel pincer hydride complex with bulky R groups on the phosphorus donor atoms. The nickel pincer hydride complexes are inactive catalysts for the hydrosilylation of CO 2 with PhSiH3.

A Bottleable Imidazole-Based Radical as a Single Electron Transfer Reagent

Das, Arpan,Ahmed, Jasimuddin,Rajendran,Adhikari, Debashis,Mandal, Swadhin K.

supporting information, p. 1246 - 1252 (2020/12/21)

Reduction of 1,3-bis(2,6-diisopropylphenyl)-2,4-diphenyl-1H-imidazol-3-ium chloride (1) resulted in the formation of the first structurally characterized imidazole-based radical 2. 2 was established as a single electron transfer reagent by treating it with an acceptor molecule tetracyanoethylene. Moreover, radical 2 was utilized as an organic electron donor in a number of organic transformations such as in activation of an aryl-halide bond, alkene hydrosilylation, and in catalytic reduction of CO2 to methoxyborane, all under ambient temperature and pressure.

Transforming atmospheric CO2 into alternative fuels: A metal-free approach under ambient conditions

Chandra Sau, Samaresh,Bhattacharjee, Rameswar,Hota, Pradip Kumar,Vardhanapu, Pavan K.,Vijaykumar, Gonela,Govindarajan,Datta, Ayan,Mandal, Swadhin K.

, p. 1879 - 1884 (2019/02/12)

This work demonstrates the first-ever completely metal-free approach to the capture of CO2 from air followed by reduction to methoxyborane (which produces methanol on hydrolysis) or sodium formate (which produces formic acid on hydrolysis) under ambient conditions. This was accomplished using an abnormal N-heterocyclic carbene (aNHC)-borane adduct. The intermediate involved in CO2 capture (aNHC-H, HCOO, B(OH)3) was structurally characterized by single-crystal X-ray diffraction. Interestingly, the captured CO2 can be released by heating the intermediate, or by passing this compound through an ion-exchange resin. The capture of CO2 from air can even proceed in the solid state via the formation of a bicarbonate complex (aNHC-H, HCO3, B(OH)3), which was also structurally characterized. A detailed mechanism for this process is proposed based on tandem density functional theory calculations and experiments.

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