3808-08-0

Upstream product

• 128342-60-9 potassium salt of N-diisopropoxyphosphorylbenzamide 
• 1246609-31-3 C₁₃H₁₉NO₂PS₂^(1-)*C₂₄H₂₀P⁽¹⁺⁾ 
• 1380596-75-7 C₁₃H₁₉NO₃PS^(1-)*C₂₄H₂₀P⁽¹⁺⁾ 
• 66078-55-5 N-(diisopropoxythiophosphoryl)thiobenzamide 
• 71039-21-9 N-diisopropoxyphosphorylthiobenzamide 

Downstream Products

• 128342-60-9 potassium salt of N-diisopropoxyphosphorylbenzamide 
• 131716-94-4 diisopropyl benzoylamidophosphate, sodium salt 
• 183606-66-8 N-diisopropoxyphosphinoylbenzamide stannic chloride complex 
• 128342-64-3 N-benzoyl-O-methyl-O,O-diisopropylmonophosphazene 

Relevant academic research and scientific papers

Synthesis of tetraphenylphosphonium (thio)phosphorylthiobenzamides and hydrolytic degradation to Ph3P=O, H2S and phosphoryl(thio)benzamides: A route for crystal design of PhC(X)NHP(O)(OiPr) 2 (X=S, O)

Reactions of the sodium salts of PhC(S)NHP(Y)(OiPr)2 (Y=S, HLI; O, HLII) with PPh4Br in 96% aqueous EtOH leads to the corresponding compounds PPh4LI,II. The structures of these compounds we

REACTIONS OF N-PHOSPHORYLATED AMIDES AND THIOAMIDES WITH ALKYL HALIDES

N-Phosphorylated thioamides and also their alkali-metal salts are easily alkylated by alkyl halides at the sulfur atom of the thiocarbonyl group, and in this process the reactivities of the alkyl halides decrease in the sequence: primary>secondary>tertiary. N-Phosphorylated amides do not react with alkyl halides, whereas their alkali-metal salts form easily hydrolyzable products of alkylation at the sulfur or oxygen atom of the P=X group of the monophosphazene structure. Alkylation reactions of N-phosphorylated amides and thioamides take only one course: The formation of products of alkylation at the nitrogen atom is not observed.