38080-06-7Relevant academic research and scientific papers
Synthesis of Tridentate Phosphine Ligands RP2 (Y = OR' or CO2R', n = 1 or 2) and Some Bidentate Chiral Phosphines R2PCH(CH3)CO2Me
Wolfsberger, Werner,Bank, Juergen,Werner, Helmut
, p. 1319 - 1328 (2007/10/03)
The bis(γ-alkoxypropyl)phosphines RP(CH2CH2OR')2 1-4 were prepared by the reaction of RPLi2 (generated by lithiation of RPH2 with n-BuLi) with ClCH2CH2OR'.Deprotonation of the alkyl group R of RPH2 by n-BuLi and other side reactions leading preferably to
ELECTROCHEMICAL SYNTHESIS OF TERTIARY PHOSPHINES FROM ORGANIC HALIDES AND CHLOROPHOSPHINES
Folest, J. C.,Nedelec, J. Y.,Perichon, J.
, p. 1885 - 1886 (2007/10/02)
The electrochemical synthesis of a wide range of tertiary mono- and diphosphines has been achieved in very simple and mild conditions, in an undivided electrolytic cell with a sacrificial anode of magnesium.
