380886-45-3

Basic information

• Product Name: D-p-chlorophenyl 2-phthalimidoxy-4-methylpentanoamide
• Synonyms: D-p-chlorophenyl 2-phthalimidoxy-4-methylpentanoamide
• CAS NO: 380886-45-3
• Molecular Weight: 386.835
• Mol File: 380886-45-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: D-p-chlorophenyl 2-phthalimidoxy-4-methylpentanoamide(CAS DataBase Reference)
• NIST Chemistry Reference: D-p-chlorophenyl 2-phthalimidoxy-4-methylpentanoamide(380886-45-3)
• EPA Substance Registry System: D-p-chlorophenyl 2-phthalimidoxy-4-methylpentanoamide(380886-45-3)

Safety Data

• Hazardous Substances Data: 380886-45-3(Hazardous Substances Data)

Upstream product

• 380886-35-1 D-tert-butyl 2-phthalimid-N-oxy-4-methylpentanoate 
• 3069-50-9 O-acetyl-L-α-hydroxyisocapric acid 
• 13748-90-8 (S)-2-hydroxyl-3,3-dimethylbutyric acid 
• 61-90-5 L-leucine 
• 106-47-8 4-chloro-aniline 
• 310404-45-6 (R)-4-methyl-2-phthalimidooxypentanoic acid 
• 3069-51-0 L-α-Acetoxyisocapronsaeure-tert-butylester 
• 3069-52-1 (2S)-2-hydroxy-4-methylpentanoic acid 1,1-dimethylethyl ester 

Relevant articles and documents

Synthesis and characterization of chiral N-O turns induced by α-aminoxy acids

Chiral α-aminoxy acids of various side chains were synthesized with high optical purity starting from chiral α-amino acids. The conformations of diamides 13a-e, 15, and 16 were probed by using NMR, FT-IR, and CD spectroscopic methods as well as X-ray crystallography. The right-handed turns with eight-membered-ring intramolecular hydrogen bonds between adjacent residues (called the N-O turns) were found to be preferred for D-aminoxy acid residues, and they were independent of the side chains. The rigid chiral N-O turns should have great potential in molecular design.