380892-89-7Relevant academic research and scientific papers
Synthesis of N-protected allylic amines from allyl ethers
Kim, Ji Duck,Lee, Min Hee,Han, Gyoonhee,Park, Hyunju,Zee, Ok Pyo,Jung, Young Hoon
, p. 8257 - 8266 (2007/10/03)
A synthetic method for N-protected allylic amines from allyl ethers using chlorosulfonyl isocyanate (CSI) is presented. The reaction of 4-phenylbut-2-enyl methyl ether (1i) with CSI afforded methyl N-(1-benzylallyl)carbamate (2i) and methyl N-(4-phenylbut
Carbonylation of allylic ethers to esters
-
, (2008/06/13)
A method is disclosed for the production of esters by reaction of an allylic ether with carbon monoxide in the presence of a catalytically effective amount of a Group VIII noble metal catalyst and halide compound to obtain esters. The halide compound is present in an amount sufficient to prevent the catalyst from being converted into a Group VIII metal during the reaction. When the reaction is conducted in the presence of a quaternary ammonium salt the ester may be extracted by solvent extraction to minimize catalyst decomposition caused when extractive distillation is used to separate the ester.
