38121-24-3Relevant articles and documents
Palladium(II)-catalyzed conjugate addition of arylsiloxanes in water
Lerebours, Rachel,Wolf, Christian
, p. 2737 - 2740 (2007)
Equation Presented Palladium-phosphinous acids catalyze the conjugate addition of arylsiloxanes to a wide range of α.β-unsaturated substrates in water microwave-assisted procedure is described that uses 5 mol % of POPd1 to afford /-substituted ketones, aldehydes, esters, nitriles, an nitroalkanes in 83% to 96% yield within 4 h. This method eliminates the need for stoichiometric additives and an excess of arylsiloxane, an does not require an inert atmosphere.
