381218-92-4

Upstream product

• 89972-76-9 4'-(4-bromo-phenyl)-[2,2';6',2'']terpyridine 
• 201733-56-4 2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane 

Downstream Products

• 1185464-52-1 [Ir(2-(2,4-difluorophenyl)pyridine(-1H))2((C₅H₃NC₆H₄C₅H₂N(C₅H₄N)2)2)][PF₆] 
• 1227748-51-7 3,3'-(perfluorocyclopent-1-ene-1,2-diyl)bis(2-methyl-6-(4-(2,2':6',2''-terpyridin-4'-yl)phenyl)benzo[b]thiophene) 
• 381218-96-8 4′-(4-boronatophenyl)-2,2′:6′,2′′-terpyridine 

Relevant academic research and scientific papers

Palladium-catalysed cross-coupling reactions of ruthenium bis-terpyridyl complexes: Strategies for the incorporation and exploitation of boronic acid functionality

The palladium catalysed Miyaura cross-coupling reactions of 4′-(4-bromophenyl)-2,2′:6′,2″-terpyridine (tpy-φ-Br) and 4′-bromo-2,2′:6′,2″-terpyridine (tpy-Br) with bis(neopentyl glycolato)diboron (B2neo2 lead to the first reported exa

Luminescent infinite coordination polymer materials from metal-terpyridine ligation

A new class of infinite coordination polymers (CP) was synthesized using a tetrahedral tetrakis[4-(4′-phenyl-2,2′:6′,2′′- terpyridine)phenyl]methane ligand as an organic node to direct the three-dimensional growth of the network and MII (M = Zn, Fe, Ni, and Ru) ions as inorganic linkers, an approach that is the opposite of the metal-as-a-node strategy used in the construction of metal-organic frameworks (MOFs). The unusual rod-like morphology of the resulting microporous materials can be tuned via solvents and reaction conditions. The covalent entrapment of a [Ru(tpy)2]2+ moiety in the skeleton of the 3D-network enables the Ru-CP to exhibit room-temperature luminescence.

A perfluorocyclopentene based diarylethene bearing two terpyridine moieties - Synthesis, photochemical properties and influence of transition metal ions

The synthesis of a perfluorocyclopentene based diarylethene bearing two terpyridine units is reported. Furthermore studies of the free ligand's photochromism and investigations regarding the influence of various transition metal ions on the photochromic reaction are presented. The photochromism of the central diarylethene unit is strongly dependent on the transition metal present, vice versa the photochromic reaction seems to influence the MLCT transition of a binuclear Ru(II) complex.