38131-83-8Relevant academic research and scientific papers
Transition-Metal-Free Dehydrogenative N–N Coupling of Secondary Amines with KI/KIO4
Yin, Dehang,Jin, Jian
, p. 5646 - 5649 (2019)
A transition-metal-free method for the dehydrogenative N–N coupling of secondary amines has been accomplished. This oxidative KI/KIO4 protocol is mild and operationally simple. A diverse range of diphenylamines, carbazoles, and N-alkylanilines readily undergo N–N homo-coupling effectively. Notably, the N–N cross-coupling of two different arylamines is also demonstrated, which provides a straightforward approach to the complex N–N structures.
Facile Cu(I)-catalyzed oxidative coupling of anilines to azo compounds and hydrazines with diaziridinone under mild conditions
Zhu, Yingguang,Shi, Yian
supporting information, p. 1942 - 1945 (2013/06/04)
A mild and highly efficient Cu(I)-catalyzed oxidative coupling of anilines is described. Various primary and secondary anilines can be efficiently coupled under mild conditions to the corresponding azo compounds and hydrazines in high yields. This method provides a direct and practical access to these compounds and is also amenable to gram scale with no special precautions to exclude air or moisture.
