38184-64-4Relevant articles and documents
Polysulfonate supported chiral diamine-nickel catalysts: Synthesis and applications
Zhou, Jing-xuan,Zhu, Dong-yu,Chen, Jie,Zhang, Xue-jing,Yan, Ming,Chan, Albert S.C.
supporting information, (2021/01/25)
A series of chiral polysulfonate cyclohexyldiamine-Ni(II) catalysts were prepared via sulfur (VI) fluoride exchange click-reactions. The catalysts exhibited good catalytic activity and enantioselectivity in the Michael addition of malonates to nitroalkene
Synthesis of N-Acyl Sulfamates from Fluorosulfates and Amides
Gilles, Philippe,Veryser, Cedrick,Vangrunderbeeck, Sarah,Ceusters, Sam,Van Meervelt, Luc,De Borggraeve, Wim M.
, p. 1070 - 1078 (2019/01/24)
A novel synthetic strategy toward N-acyl sulfamates was developed. Interestingly, fluorosulfates, a new emerging class of electrophiles, were used to construct the sulfamate core. This precludes handling of chlorosulfonyl isocyanate and sulfamoyl chloride
Sulfur(VI) fluoride compounds and methods for the preparation thereof
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Page/Page column 19; 20; 56, (2018/11/23)
This application describes a compound represented by Formula (I): (I) wherein: Y is a biologically active organic core group comprising one or more of an aryl group, a heteroaryl aryl group, a nonaromatic hydrocarbyl group, and a nonaromatic heterocyclic group, to which Z is covalently bonded; n is 1, 2, 3, 4 or 5; m is 1 or 2; Z is O, NR, or N; X1 is a covalent bond or —CH2CH2—, X2 is O or NR; and R comprises H or a substituted or unsubstituted group selected from an aryl group, a heteroaryl aryl group, a nonaromatic hydrocarbyl group, and a nonaromatic heterocyclic group. Methods of preparing the compounds, methods of using the compounds, and pharmaceutical compositions comprising the compounds are described as well.
