382165-40-4Relevant academic research and scientific papers
A geometrical isomeric pair of novel cobalt(III) complexes containing diphenylphosphine: Cis- and trans-[Co(dtc)2(PHPh2)2]BF4(dtc = N,N-dimethyldithiocarbamate)
Suzuki, Takayoshi,Iwatsuki, Satoshi,Takagi, Hideo D.,Kashiwabara, Kazuo
, p. 1068 - 1069 (2001)
The stable title cobalt(III) complexes containing PHPh2 have been prepared and investigated for their crystal structures and spectroscopic properties. The cis-isomer was converted photochemically to the trans-isomer, which isomerized thermally to the original cis-isomer. The structural parameters and the ligand-field strengths of the PHPh2 complexes were not predictable from the σ-donicity of PHPh2.
