38229-73-1Relevant academic research and scientific papers
Synthesis of N-Acetylglucosamine Aryl β-Glycosides Catalyzed by Crown Compounds
Kur'yanov,Chupakhina,Zemlyakov,Kotlyar,Kamalov,Chirva
, p. 385 - 389 (2007/10/03)
Glycosylation of various phenols with α-D-glucosaminyl chloride peracetate in a solid phase-liquid system catalyzed by crown compounds was studied. The highest yields of aryl β-glycosides were observed at room temperature in acetonitrile using anhydrous p
Carbohydrate protein interactions. Syntheses of agglutination inhibitors of wheat germ agglutinin by phase transfer catalysis
Roy, Rene,Tropper, Francois D.
, p. 817 - 821 (2007/10/02)
Starting from chloride 1, a series of para-substituted aryl 2-acetamido-2-deoxy-β-D-glucopyranosides were prepared using phase transfer catalysis conditions with tetrabutylammonium hydrogen sulfate in 1 M sodium hydroxide and methylene chloride at room temperature.Zemplen de-O-acetylation afforded the unprotected glycosides.Optimization of reaction conditions was evaluated.Several functional group manipulations were effected to widen the number and nature of the para-substituents. Key words: phase transfer catalysis, aryl 2-acetamido-2-deoxy-β-D-glucopyranosides.
