38256-03-0

Basic information

• Product Name: 2-tricyclo[3.3.1.1^3,7]decyllithium
• Synonyms: 2-tricyclo[3.3.1.1^3,7]decyllithium
• CAS NO: 38256-03-0
• Molecular Weight: 142.17
• Mol File: 38256-03-0.mol

Chemical Properties

• CAS DataBase Reference: 2-tricyclo[3.3.1.1^3,7]decyllithium(CAS DataBase Reference)
• NIST Chemistry Reference: 2-tricyclo[3.3.1.1^3,7]decyllithium(38256-03-0)
• EPA Substance Registry System: 2-tricyclo[3.3.1.1^3,7]decyllithium(38256-03-0)

Safety Data

• Hazardous Substances Data: 38256-03-0(Hazardous Substances Data)

Upstream product

• 7346-41-0 2-chloroadamantane 

Downstream Products

• 152530-56-8 1-(1-azabicyclo[3.3.0]octan-5-yl)-1-(4-(2-methyl-1,3-oxathiolane-2-yl)phenyl)-1-(2-tricyclo[3.3.1.1^3,7]decyl)methan-1-ol 

Relevant articles and documents

High-Yield Direct Synthesis of a New Class of Tertiary Organolithium Derivatives of Polycyclic Hydrocarbons

For the first time, 1- and 2-adamantyllithium, 1-diamantyllithium, 3,5,7-trimethyl-1-adamantyllithium, 1-twistyllithium, 3-methyl-7-noradamantyllithium, 1-triptycyllithium, and 3-homoadamantyllithium have been directly synthesized from the reaction of an organic halide and lithium metal.By use of certain experimental parameters, the phenomena at the metal-solution interface are controlled, thereby resulting in exceptionally high yields of this new class of organometallic compounds (>75percent, except in the case of 3-homoadamantyllithium).Competition between formation of the organometallic compound and formation of solvent-attack byproducts is determined by the degree of adsorption of the transient species (anion radical RX-. or radical pair R..Li) generated at the metal surface during attack by the halogenated derivative.