383417-70-7

Upstream product

• 2936-70-1 (2R,3S,4S,5R,6S)-2-Hydroxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3,4,5-triol 
• 71676-30-7 phenyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside 
• 604-69-3 β-D-glucose pentaacetate 
• 13992-16-0 (2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3,4,5-triyl triacetate 
• 101696-02-0 phenyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-1-thio-β-D-glucopyranoside 
• 108-98-5 thiophenol 

Downstream Products

• 383417-86-5 Benzoic acid (2S,3R,4S,5R,6R)-5-benzyloxy-6-benzyloxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-2-phenylsulfanyl-tetrahydro-pyran-3-yl ester 
• 570400-16-7 Benzoic acid (2S,3R,4S,5R,6R)-5-benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-6-(9H-fluoren-9-ylmethoxycarbonyloxymethyl)-2-phenylsulfanyl-tetrahydro-pyran-3-yl ester 
• 570400-15-6 Benzoic acid (2S,3R,4S,5R,6R)-5-benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-6-(4-oxo-pentanoyloxymethyl)-2-phenylsulfanyl-tetrahydro-pyran-3-yl ester 
• 570400-14-5 Benzoic acid (2S,3R,4S,5R,6R)-6-allyloxycarbonyloxymethyl-5-benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-2-phenylsulfanyl-tetrahydro-pyran-3-yl ester 
• 570400-12-3 C₅₁H₅₀O₁₅ 
• 185994-25-6 Benzoic acid (2S,3R,4S,5R,6R)-5-benzyloxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-4-(9H-fluoren-9-ylmethoxycarbonyloxy)-2-phenylsulfanyl-tetrahydro-pyran-3-yl ester 
• 404875-54-3 C₆₆H₇₂O₁₂SSi 
• 1054621-94-1 4-Methoxy-benzoic acid (2R,3R,4S,5R,6R)-2-((2R,3S,4S,5R,6S)-5-benzoyloxy-3-benzyloxy-4-hydroxy-6-phenylsulfanyl-tetrahydro-pyran-2-ylmethoxy)-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester 
• 185994-26-7 phenylthio 2-O-benzoyl-4-O-benzyl-β-D-glucopyranoside 

Relevant academic research and scientific papers

Parallel synthesis of multi-branched oligosaccharides related to elicitor active pentasaccharide in rice cell based on orthogonal deprotection and glycosylation strategy

We describe a parallel and efficient synthesis of multi-branched oligosaccharides 3a-g based upon the structure of the phytoalexin elicitor active branched pentasaccharide 2. One-pot sequential orthogonal deprotection of tetrasaccharide 5 with three different protecting groups provided each of seven glycosyl acceptors 4a-g. Glycosylation of the acceptors 4a-g, followed by deprotection provided branched oligosaccharides 3a-g. All the reaction processes from scaffold 5 to 3a-g except for final hydrogenolysis were achieved utilizing an automated synthesizer in a parallel fashion.

The first synthesis of tetraglucosyl glucitol having phytoalexin-elicitor activity in rice cells based on a sequential glycosylation strategy

We describe a highly convergent approach for the synthesis of the tetraglucosyl glucitol 1 and its derivatives 4, 5 and 6 which exhibit phytoalexin-elicitor activity in rice cells based on sequential glycosylation.