38344-42-2Relevant articles and documents
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Isaeva,Z.G. et al.
, (1965)
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Reactions of allyl alcohols of the pinane series and of their epoxides in the presence of montmorillonite clay
Il'ina, Irina V.,Volcho, Konstantin P.,Korchagina, Dina V.,Barkhash, Vladimir A.,Salakhutdinov, Nariman F.
, p. 353 - 368 (2008/02/08)
The reactivity of allyl alcohols of the pinane series and of their epoxides in the presence of montmorillonite clay in intra- and intermolecular reactions was studied. Mutual transformations of (+)-trans-pino-carveol ((+)-2) and (-)-myrtenol ((-)-3a) were major reactions of these compounds on askanite-bentonite clay (Schemes 1 and 2). However, the two reactions gave different isomerization products, indicating that the reactivity of the starting alcohol (+)-2 or (-)-3a was different from that of the same compound (+)-2 or (-)-3 formed in the course of the reactions, (-)-cis- and (+)-trans-Verbenol ((-)-16 and (+)-12, resp.), as well as (-)-cis-verbenol epoxide ((-)-20) reacted with both aliphatic and aromatic aldehydes on askanite-bentonite clay giving various heterocyclic compounds (Schemes 4, 5 and 7); the reaction path depended on the structure of both the terpenoid and the aldehyde.
Pheromone Synthesis, CIV.- Synthesis of the Enantiomers of α-Phellandren-8-ol (p-Mentha-1,5-dien-8-ol), a Monoterpene from Bark Beetles
Mori, Kenji,Igarashi, Yasuhiro
, p. 93 - 96 (2007/10/02)
Enantiomerically pure (R)-α-phellandren-8-ol (p-mentha-1,5-dien-8-ol, 1a) was synthesized from (R)-carvone (2).Similarly (S)-1a was synthesized from (S)-2.
