38351-01-8

Basic information

• Product Name: 1,1'-Biphenyl, 2-methyl-2'-(methylthio)-
• CAS NO: 38351-01-8
• Molecular Formula: C14H14S
• Mol File: 38351-01-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1'-Biphenyl, 2-methyl-2'-(methylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-Biphenyl, 2-methyl-2'-(methylthio)-(38351-01-8)
• EPA Substance Registry System: 1,1'-Biphenyl, 2-methyl-2'-(methylthio)-(38351-01-8)

Safety Data

• Hazardous Substances Data: 38351-01-8(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 132-65-0 dibenzothiophene 
• 74-88-4 methyl iodide 

Downstream Products

• 31317-07-4 1-methyldibenzo[b,d]thiophene 

Relevant articles and documents

Regiochemistry and Stereochemistry of Nickel-Promoted, Carbon-Carbon Bond-Forming Reactions of Cyclic Sulfur Compounds

Reaction of methylmagnesium iodide and phenylmagnesium bromide with thianaphthene, dibenzothiophenone, thianthrene, and 2,3-dihydrothiapyran in the presence of nickel dichloride have been shown to yield, regioselectively in most cases, ring-opened products in which the carbon-sulfur bonds have been replaced by carbon-carbon bonds.Stereospecific carbon-carbon bond formation has taken place in the reactions of thianaphthene and 2,3-dihydrothiapyran, the products having maintained the cis-olefin configuration of the starting sulfur compounds.Isomerization into the more stable compounds has been observed in some cases.