383889-16-5Relevant academic research and scientific papers
Synthesis, characterization and cancer cell growth inhibition activity of ruthenium(II) complexes bearing bidentate pyrrole-imine ligands
Chen, Guan-Hao,Leu, Wohn-Jenn,Guh, Jih-Hwa,Lin, Chia-Her,Huang, Jui-Hsien
, p. 122 - 130 (2018/05/28)
A series of bidentate pyrrole-imine ligands, [C4H3NH-(2-CH=N-R)] (1, R = cyclohexenyl; 2, R = CH2CH2-1-cyclohexenyl; 3, R = tBu; 4, R = CH2-2-furyl; 5, R = 2-methoxylphenyl; 6, R = phenyl;
Rare earth metal bis(trimethylsilyl)amido complexes bearing pyrrolyl-methylamide ligand. Synthesis, structure, and catalytic activity towards guanylation of amines
Liu, Chao,Zhou, Shuangliu,Wang, Shaowu,Zhang, Lijun,Yang, Gaosheng
experimental part, p. 8994 - 8999 (2011/01/08)
The N-arylaminomethyl substituted pyrrolyl ligand 2-[(2,4,6-Me 3C6H2)NHCH2](C4H 3NH) (1) was synthesized by reduction of 2-[(2,4,6-Me 3C6H2)NCH](C4H3NH) using NaBH4. Treatment of [(Me3Si)2N] 3Ln(μ-Cl)Li(THF)3 with 1 equiv. of 1 in reflux toluene for 24 h, afforded the corresponding trivalent rare earth metal amides with formula {(μ-η5:η1):η1-2-[(2,4,6- Me3C6H2)NCH2]C4H 3N]LnN(SiMe3)2}2 (Ln = Y(2), Nd(3), Sm(4), Dy(5), Er(6)). All compounds were fully characterised by spectroscopic methods and elemental analyses. The structures of complexes 2, 4 and 6 were determined by single-crystal X-ray analyses. X-Ray analyses discovered that two rare-earth metal ions were bridged by dianion ligand with the pyrrolyl ring which coordinated to one rare earth metal in an η5 mode, the tethered nitrogen anion and nitrogen atom of the pyrrolyl ring coordinated to another rare earth metal in η1 modes forming the centrosymmetric dinuclear structures. The rare earth metal complexes as catalysts for the guanylation of aromatic amines were studied. Results showed all rare earth metal complexes exhibited a high catalytic activity on the guanylation of aromatic amines. The Royal Society of Chemistry 2010.
Chelating N-pyrrolylphosphino-N′-arylaldimine ligands: Synthesis, ligand behaviour and applications in catalysis
Anderson, Carly E.,Batsanov, Andrei S.,Dyer, Philip W.,Fawcett, John,Howard, Judith A. K.
, p. 5362 - 5378 (2007/10/03)
Two families of variously-substituted N-pyrrolylphosphino-N′- arylaldimine ligands, 2-(aryl-NCH)C4H3N-PR2 {3a-d R = Ph; 4a-d R = Pri2N}, have been prepared from the corresponding pyrrolylaldimines 2.
