3840-18-4

Basic information

• Product Name: 2-(2-Methylphenoxy)aniline
• Synonyms: 2-(2-methylphenoxy)-benzenamin;2-(o-tolyloxy)-anilin;aminomethyldiphenylether;Aniline, 2-(o-tolyloxy)-;Benzenamine, 2-(2-methylphenoxy)-;2-(2-METHYLPHENOXY)ANILINE;2-AMINOPHENYL O-TOLYL ETHER;2-AMINO-2'-METHYLDIPHENYL ETHER
• CAS NO: 3840-18-4
• Molecular Formula: C₁₃H₁₃NO
• Molecular Weight: 199.25
• EINECS: 223-329-3
• Product Categories: Biphenyl & Diphenyl ether
• Mol File: 3840-18-4.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 196 °C / 23mmHg
• Flash Point: 133.281 °C
• Appearance: /
• Density: 1.11
• Vapor Pressure: 0.00117mmHg at 25°C
• Refractive Index: 1.6040-1.6060
• Storage Temp.: 2-8°C
• PKA: 4.00±0.10(Predicted)
• CAS DataBase Reference: 2-(2-Methylphenoxy)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-Methylphenoxy)aniline(3840-18-4)
• EPA Substance Registry System: 2-(2-Methylphenoxy)aniline(3840-18-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• RTECS: BY9750000
• HazardClass: IRRITANT
• Hazardous Substances Data: 3840-18-4(Hazardous Substances Data)

Usage

Application

2-(2-Methylphenoxy)aniline is a useful research chemical.

InChI:InChI=1/C13H13NO/c1-10-6-2-4-8-12(10)15-13-9-5-3-7-11(13)14/h2-9H,14H2,1H3

Upstream product

• 88-73-3 2-Chloronitrobenzene 
• 95-48-7 ortho-cresol 
• 3235-09-4 potassium o-cresolate 
• 54106-40-0 1-methyl-2-(2-nitrophenoxy)benzene 
• 1493-27-2 ortho-nitrofluorobenzene 

Downstream Products

• 35486-82-9 4-amino-9H-xanthen-9-one 
• 1071865-97-8 (3R)-tert-butyl 3-(1-(2-(o-tolyloxy)phenyl)-1-hydroxy-5-methoxypentyl)piperidine-1-carboxylate 
• 860525-76-4 dichloro-(2-o-tolyloxy-phenyl)-arsine 
• 794518-74-4 2-(2-acetylamino-phenoxy)-benzoic acid 
• 76840-92-1 Imidazolidin-2-ylidene-(2-o-tolyloxy-phenyl)-amine 
• 76838-99-8 (2-o-Tolyloxy-phenyl)-thiourea 
• 884512-16-7 1-iodo-2-(2-tolyloxy)benzene 

Relevant articles and documents

Design, synthesis and antifungal activity of novel furancarboxamide derivatives

Twenty-seven novel furancarboxamide derivatives with a diphenyl ether moiety were synthesized and evaluated for their antifungal activity against Rhizoctonia solani, Botrytis cirerea, Valsa Mali and Sphaceloma ampelimum. Antifungal bioassay results indicated that most compounds had good or excellent fungicidal activities for R. solani and S. ampelimum at 20 mg L-1. Among synthesized compounds, compound 18e showed a greater inhibitory effect against S. ampelimum, with half maximal effective concentration (EC50) values of 0.020 mg L-1. This strong activity rivals currently used commercial fungicides, such as Boscalid and Carbendazim, and has great potential as a lead compound for future development of novel fungicides.

Synthesis and enantioselective hydrogenation of seven-membered cyclic imines: Substituted dibenzo[b,f][1,4]oxazepines

Highly enantioselective hydrogenation of seven-membered cyclic imines, substituted dibenzo[b,f][1,4]oxazepines, was achieved, with up to 94% ee, by using the [Ir(COD)Cl]2/(S)-Xyl-C3*-TunePhos complex as the catalyst in the presence of morpholine-HCl.