38412-84-9

Upstream product

• 65137-45-3 2-methyl-5-(1,2,2-trimethylcyclopentyl)phenol 
• 1026748-52-6 4-(Tetrahydro-pyran-2-yloxy)-3-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohex-2-enone 
• 153582-11-7 tert-Butyl-dimethyl-((1S,6S)-2,2,6-trimethyl-7-oxa-bicyclo[4.1.0]hept-1-ylmethoxy)-silane 
• 153582-12-8 2-(tert-butyl-dimethyl-silanyloxy)-1-(1,2,2-trimethyl-cyclopentyl)-ethanone 
• 179944-42-4 (1'S)-1-(1',2',2'-trimethylcyclopentyl)hexane-1,5-dione 
• 179944-43-5 (1'S)-3-(1',2',2'-trimethylcyclopentyl)-2-cyclohexen-1-one 
• 88794-46-1 (-)-2,2,6-trimethyl-7-oxabicyclo[4.1.0]heptane-1-methanol 
• 472-20-8 β-cyclogeraniol 
• 79-77-6 (E)-β-ionone 
• 1026639-32-6 6-Methyl-6-phenylselanyl-3-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohex-2-enone 
• 179944-47-9 Trimethyl-[2-methyl-5-((S)-1,2,2-trimethyl-cyclopentyl)-cyclohexa-1,5-dienyloxy]-silane 

Downstream Products

• 52528-88-8 (S)-2-Benzoyloxycuparen 
• 85526-56-3 (S)-3-methyl-6-(1,2,2-trimethylcyclopentyl)benzene-1,2-diol 
• 28917-12-6 (-)-2-(1,2,2-trimethyl)-cyclopentyl-6-methyl-1,4-quinone 

Relevant academic research and scientific papers

Total synthesis of (+)-aquaticol by biomimetic phenol dearomatization: Double diastereofacial differentiation in the Diels-Alder dimerization of orthoquinols with a C2-symmetric transition state

(Chemical Equation Presented) Double or nothing: The bissesquiterpene (+)-aquaticol was synthesized by biomimetic oxidative dearomatization of 1 via an orthoquinol intermediate that undergoes spontaneous and selective dimerization; only like diastereomers

Enantioselective synthesis of cuparane sesquiterpenes. Synthesis of (-)-cuparene and (-)-δ-cuparenol

(-)-Cuparene and (-)-δ-cuparenol, two cuparane-type sesquiterpenoids, were synthesized from β-cyclogeraniol in 47% and 27% overall yield, respectively, using a Katsuki-Sharpless asymmetric epoxidation, a pinacollic rearrangement, and a Robinson annulation as key synthetic steps.