3842-72-6Relevant articles and documents
Synthesis of a H-Sulfo-POSS catalyst and application in the acetalization of glycerol with 2-butanone to yield a biofuel additive
Esteban, Jesús,S?derholm, Viktor,Vogt, Dieter
, p. 4529 - 4538 (2021/07/12)
Nanosized polyhedral oligomeric silsesquioxanes (POSS) have been employed as molecular weight enlarged structures for different purposes owing to their ease of synthesis and modification. In this work, the commercially available compound octaphenyl-POSS has been modified with chlorosulfonic acid to obtain multifunctional acidic materials (H-Sulfo-POSS) with different degrees of functionality in the structure. The synthesized materials have been characterized by ion exchange capacity, degree of sulfonation,1H-NMR, ATR-IR spectroscopy and SEM. These H-Sulfo-POSS nanocomposites were then applied to the acetalization of glycerol with 2-butanone to yield the corresponding ketal, which is a product of interest as an oxygenate fuel additive. The catalytic activity in dynamic experiments of the H-Sulfo-POSS (2601 h?1) material with the highest degree of sulfonation was even higher than that shown by the molecular catalystpara-toluene sulfonic acid (PTSA) (2256 h?1) and better than Amberlyst 36 (213 h?1); however, upon recycling by centrifugation of the catalyst, the activity of this material was not very stable. On the other hand, the material with the lowest degree of sulfonation showed not only higher activity than Amberlyst 36, but also very stable activity after reutilization throughout 10 runs.
Method for preparing ketal glycerine and/or acetal glycerine by catalyzing glycerine
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Paragraph 0174-0175; 0193, (2020/07/02)
The invention relates to a method for preparing ketal glycerine and/or acetal glycerine by catalyzing glycerine. The method comprises the following steps: contacting glycerine and a reaction raw material with a catalyst in a reactor, and reacting to obtain a product containing ketal glycerine and/or acetal glycerine, wherein the reaction raw materials contains aldehyde and/or ketone, the molar ratio of glycerine to aldehyde and/or ketone is 1:(1-10), the reaction temperature is 30-180 DEG C, the reaction time is 1-10 hours, the catalyst contains a tin-silicon molecular sieve, and the weight ratio of glycerine to the tin-silicon molecular sieve based on dry basis weight is (1-40):1, the tin-silicon molecular sieve contains a silicon element, a tin element and an oxygen element, a cavity orcavity structure is formed in all or part of crystal grains, the total specific surface area is larger than or equal to 300 m/g, and the proportion of the external specific surface area to the total specific surface area is larger than or equal to 10%. The method provided by the invention has high aldehyde/ketone conversion rate and high acetal/ketal glycerine selectivity.
COALESCING AGENT DERIVED FROM DIOXOLANE DERIVATIVES
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Paragraph 0071-0072, (2019/07/10)
The present invention relates to a coalescing agent as represented in structure (I); wherein; n is integer from 1 to 8; R1 and R2 independently represent group selected from hydrogen atom, alkyl, alkenyl, alkynyl, phenyl, benzyl groups, or optionally cyclic hydrocarbon containing heteroatom; and Y represents group selected from alkyl, alkenyl, alkynyl, phenyl, benzyl groups, or cyclic hydrocarbon containing heteroatom. The said coalescing agent can be used in coating application with efficacy to provide smooth consistent film with chemical and scratch resistant and has no pungent odour, wherein the preparation method of this compound is simplify and employs less harmful chemicals.