38420-05-2Relevant academic research and scientific papers
ANOMERIC EFFECT OF RADICALS
Giese, B.,Dupuis, J.
, p. 1349 - 1352 (2007/10/02)
The glucosyl radical 1 is attacked predominately at the axial position.This can be explained by an anomeric effect that stabilizes ?-radical 5.
REDUCTION STEREOSELECTIVE D'HALOGENURES DE GLYCOSYLES PAR LE DEUTERIEURE DE TRIBUTYLETAIN
Praly, Jean-Pierre
, p. 3075 - 3078 (2007/10/02)
The reduction of several glycosyl halides by tributyltin deuteride is shown to proceed with a high stereoselectivity, favouring α-attack.
