38425-28-4Relevant academic research and scientific papers
Chemoselective and regiospecific suzuki coupling on a multisubstituted sp3-Carbon in 1,1-diborylalkanes at room temperature
Endo, Kohei,Ohkubo, Takahiro,Hirokami, Munenao,Shibata, Takanori
supporting information; experimental part, p. 11033 - 11035 (2010/09/16)
The palladium-catalyzed Suzuki-Miyaura cross-coupling on a multisubstituted sp3-carbon in 1,1-diborylalkanes was achieved at room temperature. The generation of a monoborate intermediate by virtue of the adjacent B atom could result in the chemoselective coupling reaction under ambient conditions.
