384346-50-3Relevant academic research and scientific papers
Diastereoselective ruthenium-Cp complexation of enantiopure arene compounds possessing stereogenic benzylic alcohol functionalities
Kamikawa, Ken,Furusyo, Masaru,Uno, Takahiro,Sato, Yasuko,Konoo, Atutoshi,Bringmann, Gerhard,Uemura, Motokazu
, p. 3667 - 3670 (2001)
Figure presented R = OMe, Me, Me3Si 84-94 % up to 95/5 dr Enantiopure (arene)ruthenium compounds possessing a stereogenic benzylic alcohol functionality were stereoselectively synthesized by diastereoselective ruthenium-Cp complexation to a distinct arene face. This diastereoselective ruthenium-Cp complexation was further extended to biaryl compounds linked with a six-membered lactone bridge for the synthesis of enantiomerically pure, axially chiral biaryls.
