38476-25-4Relevant academic research and scientific papers
The photo-Wallach rearrangement. Heavy-atom kinetic isotope effects and mechanism
Shine, Henry J.,Subotkowski, Witold,Gruszecka, Ewa
, p. 1108 - 1115 (1986)
The photo-rearrangement of mixtures of azoxybenzene 4 and, successively, 4, 4, and 4 were carried out.Kinetic isotope effects (KIE) were calculated from measurements of isotopic ratios in both recovered 4 and the product, 2-hydroxya
Benzidine Rearrangements. 17. The Concerted Nature of the One-Proton p-Semidine Rearrangement of 4-Methoxyhydrazobenzene
Shine, Henry J.,Zmuda, Henryk,Kwart, Harold,Horgan, Ann Gafney,Breichbiel, Martin
, p. 5181 - 5184 (2007/10/02)
The nitrogen kinetic isotope effects (KIE) for the acid-catalyzed rearrangement of 4-methoxyhydrazobenzene (1b) into the p-semidine (4-methoxy-4'-aminodiphenylamine, 2b) and o-semidine (2-amino-5-methoxydiphenylamine, 3b) have been measured and are 1.0296
