384861-87-4

Upstream product

• 16940-66-2 sodium tetrahydroborate 
• 330583-48-7 (2,6-diethylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5-tetragermolane 
• 330583-49-8 (2,6-diethylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5,6,7-hexathiagermepane 

Downstream Products

• 912672-31-2 [(2,6-dimesitylphenyl)(2,6-diethylphenyl)Ge(μ-S)2Ru(η6-benzene)] 
• 912672-30-1 [(2,6-dimesitylphenyl)(2,6-diethylphenyl)Ge(μ-S)2Ru(η6-p-cymene)] 
• 912672-40-3 (germanium)(2,6-diethylphenyl)(2,6-dimesitylphenyl)bis-(μ-S)(ruthenium)(PPh3) 

Relevant academic research and scientific papers

Synthesis of oxo- and sulfido-bridged germanium-ruthenium complexes and reactions on the chalcogenido bridges

A series of heterodinuclear germanium-ruthenium complexes having sulfido/oxo bridges, Dmp(Dep)-Ge(μ-E1)(μ-E2) Ru(η6-arene) (E1, E2 = S, O; arene -benzene, p-cymene; Dmp = 2,6-dimesitylphenyl, Dep = 2,

Sterically protected dipotassium germanedithiolate

The germanedithiols Dmp(Ar)Ge(SH)2 [Dmp=2,6-dimesitylphenyl; Ar = Dep (2,6-diethylphenyl) 1a, Tip (2,4,6-triisopropylphenyl) 1b] were synthesized by the reduction of hexathiagermepanes Dmp(Ar)GeS6 and tetrathiagermolanes Dmp(Ar)GeS4 with NaBH4. The treatment of 1a with 2 equiv of potassium hydride afforded the dipotassium germanedithiolate 2.