38527-56-9Relevant articles and documents
7-oxabicyclo[2.2.1]heptadiene derivatives: Reactivity towards Bronsted acids
Maggiani, Alain,Tubul, Arlette,Brun, Pierre
, p. 2495 - 2496 (1999)
7-Oxabicyclo[2.2.1]heptadiene derivatives can be converted to phenols, fulvenes and/or the products from a retro-Diels-Alder-like reaction by treatment with Bronsted acids; the outcome of the reaction depends on the experimental conditions and the nature of the Bronsted acid used.
Efficient procedure for the preparation of 2-bromofuran and its application in the synthesis of 2-arylfurans
Raheem, Mohammed-Abdul,Nagireddy, Jaipal R.,Durham, Robin,Tam, William
experimental part, p. 2138 - 2146 (2010/08/13)
A simple, straightforward, and scalable procedure for the preparation of 2-bromofuran using N-bromosuccinimide (NBS) in dimethylformamide (DMF) is reported. The described preparation is conducted on a 20 to 50g scale and does not require extractive workup procedures or chromatographic purifications. To illustrate the synthetic applications of 2-bromofuran, palladium-catalyzed Suzuki coupling reactions of the prepared 2-bromofuran with various aryl boronic acids were investigated, and moderate to good yields of 2-arylfurans were obtained. Copyright Taylor & Francis Group, LLC.