38527-64-9Relevant academic research and scientific papers
Manganese(III) acetate-mediated oxidative coupling of phenylhydrazines with furan and thiophene: A novel method for hetero biaryl coupling
Demir, Ayhan S.,Reis, ?mer,Emrullaho?lu, Mustafa
, p. 8055 - 8058 (2002)
A convenient new method for the arylation of furan and thiophene with arylhydrazine and manganese(III) acetate is described. Oxidation of arylhydrazines with Mn(III) acetate in furan or thiophene affords the corresponding 2-aryl-substituted furans and thiophenes in good yield using commercially available materials; access to 2-substituted heterobiaryls works selectively, and coupling occurs with loss of the hydrazine moiety.
Facile C–H arylation using catalytically active terminal sulfurs of 2 dimensional molybdenum disulfide
Hwang, Eunhee,Mi Lee, Sae,Bak, Sora,Min Hwang, Hee,Kim, Hyunjung,Lee, Hyoyoung
supporting information, p. 3969 - 3973 (2018/10/02)
The first methodology of C–H arylation of heteroarene via 2D transition metal dichalcogenides that have catalytically active edge functional groups was described. The terminal sulfur groups could effectively catalyze a formation of an azo-linked intermediate with aryl diazonium salts, leading to produce heteroarenes with good yields. This novel methodology using bulk 2D transition metal dichalcogenides that have catalytically active edge functional groups can apply for various reactions to achieve C–C bond formation in the fields of heterogeneous catalysis that is easily separable, highly reusable, and inexpensive method.
