38542-94-8

Basic information

• Product Name: AMMONIUM TRIFLUOROMETHANESULFONATE
• Synonyms: AMMONIUM TRIFLATE;AMMONIUM TRIFLUOROMETHANESULFONATE;Ammonium trifluoromethanesulfonate,99%;Ammonium trifluoromethanesulfonateAmmonium triflate;AMMoniuM trifluoroMethanesulfonate, 99% 5GR;Ammonium trifluoromethanesulfonate 99%
• CAS NO: 38542-94-8
• Molecular Formula: CHF₃O₃S*H₃N
• Molecular Weight: 167.11
• Product Categories: Ammonium;Ammonium Salts;Chemical Synthesis;Inorganic Salts;Materials Science;Metal and Ceramic Science;Salts;Synthetic Reagents
• Mol File: 38542-94-8.mol
• Article Data: 2

Chemical Properties

• Melting Point: 224-226 °C(lit.)
• Boiling Point: 245.5°C at 760 mmHg
• Flash Point: 102.2°C
• Appearance: White/Crystalline Powder
• Vapor Pressure: 0.00934mmHg at 25°C
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: AMMONIUM TRIFLUOROMETHANESULFONATE(CAS DataBase Reference)
• NIST Chemistry Reference: AMMONIUM TRIFLUOROMETHANESULFONATE(38542-94-8)
• EPA Substance Registry System: AMMONIUM TRIFLUOROMETHANESULFONATE(38542-94-8)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 38542-94-8(Hazardous Substances Data)

Usage

Chemical Properties

White crystalline powder

Uses

Ammonium Triflate is effective as a semiconductor and useful in the synthesis of symmetrical pincer ligands from the group of m terphenyl compounds.

InChI:InChI=1/CHF3O3S.H3N/c2-1(3,4)8(5,6)7;/h(H,5,6,7);1H3

Upstream product

• 7664-41-7 ammonia 
• 1493-13-6 trifluorormethanesulfonic acid 
• 140-29-4 phenylacetonitrile 
• 86-29-3 Diphenylacetonitrile 
• 12125-02-9 ammonium chloride 

Downstream Products

• 199582-23-5 OsH(P(C₆H₅)2CH₃)2(C₁₀H₈N₂)(CO)⁽¹⁺⁾*O₃SCF₃^(1-)=[OsH(P(C₆H₅)2CH₃)2(C₁₀H₈N₂)(CO)]O₃SCF₃ 
• 199582-26-8 cis,trans-[RuH(CO)(PPh3)2(2,2′-bipyridyl)][OTf] 
• 199582-25-7 OsH(P(C₆H₅)3)2(C₁₂H₈N₂)(CO)⁽¹⁺⁾*O₃SCF₃^(1-)=[OsH(P(C₆H₅)3)2(C₁₂H₈N₂)(CO)]O₃SCF₃ 
• 7727-37-9 nitrogen 
• 174899-66-2 1-(n-butyl)-3-methylimidazolium triflate 
• 121091-30-3 3-methyl-1-methylimidazolium trifluoromethanesulfonate 
• 882172-79-4 1-butyl-4-methylpyridinium trifluoromethylsulfonate 
• 1201797-51-4 [(η5-cyclopentadienyl)Ru(triphenylphosphine)2(CCHPh)]OTf 

Relevant articles and documents

Reaction of digermanes and related Ge-Si compounds with trifluoromethanesulfonic acid: Synthesis of helpful building blocks for the preparation of Ge-Ge(Si)-catenated compounds

The reaction of a series of compounds, Ar3 Ge-MR3, 1-4 (Ar=Ph, p-Tol, M=Si, Ge, R=Ph, Me, tBu), with one equivalent of trifluoromethanesulfonic acid (HOTf) was investigated. The corresponding triflates were isolated in several cases. The molecular structure of Ph3 Ge-GePh2 OTf (5) in solid state was investigated by X-ray analysis. The triflates were converted to the corresponding chlorides under the action of ammonium chloride.