38565-53-6

Basic information

• Product Name: 3-(Perfluoro-n-octyl)propenoxide
• Synonyms: DAIKIN E-1830;3-(PERFLUORO-N-OCTYL)-1,2-PROPENOXIDE;3-(PERFLUORO-N-OCTYL)PROPENOXIDE;3-PERFLUOROOCTYL-1,2-EPOXYPROPANE;3-(PERFLUOROOCTYL)-1,2-PROPENOXIDE;1,2-EPOXY-1H,1H,2H,3H,3H-HEPTADECAFLUOROUNDECANE;(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-HEPTADECAFLUORONONYL)OXIRANE;1,2-EPOXY-1H,1H,2H,3H,3H-HEPTADECAFLUOROUNDECANE 98+%
• CAS NO: 38565-53-6
• Molecular Formula: C₁₁H₅F₁₇O
• Molecular Weight: 476.13
• EINECS: 254-006-5
• Product Categories: Fluorous Chemistry;Fluorous Compounds;Oxiranes;Simple 3-Membered Ring Compounds;Synthetic Organic Chemistry;Epoxide MonomersSelf Assembly&Contact Printing;Fluorine-Containing Monomers for 157 nm UV Lithography Resist Polymers;Lithography Monomers;Monomers;Polymer Science
• Mol File: 38565-53-6.mol
• Article Data: 9

Chemical Properties

• Melting Point: 76-78 °C
• Boiling Point: 87 °C19 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: liquid
• Density: 1.712 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.745mmHg at 25°C
• Refractive Index: n20/D 1.32(lit.)
• CAS DataBase Reference: 3-(Perfluoro-n-octyl)propenoxide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(Perfluoro-n-octyl)propenoxide(38565-53-6)
• EPA Substance Registry System: 3-(Perfluoro-n-octyl)propenoxide(38565-53-6)

Safety Data

• Hazard Codes: Xi
• WGK Germany: 3
• Hazardous Substances Data: 38565-53-6(Hazardous Substances Data)

Usage

Uses

3-(Perfluorooctyl)-1,2-propenoxide is a fluorinated epoxide with antibacterial properties.

InChI:InChI=1/C11H5F17O/c12-4(13,1-3-2-29-3)5(14,15)6(16,17)7(18,19)8(20,21)9(22,23)10(24,25)11(26,27)28/h3H,1-2H2

Upstream product

• 507-63-1 1-iodoheptadecafluorooctane 
• 591-87-7 Allyl acetate 
• 99325-02-7 2-Iodo-4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecyl acetate 
• 107-18-6 allyl alcohol 
• 38550-45-7 3-perfluoro-n-octyl-2-iodo-1-propanol 
• 77758-89-5 phenyl(perfluorooctyl)iodonium triflate 

Downstream Products

• 93706-76-4 3-(Perfluorooctyl)-2-hydroxypropyl Methacrylate 
• 1456887-26-5 C₄₆H₄₉F₁₇N₄O₇ 
• 92071-84-6 1-trimethylammonium-4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundecan-2-ol, iodide 
• 94159-84-9 1H,1H,2H,3H,3H-Perfluoro-1,2,-undecanediol 
• 94159-88-3 4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononan-1-yl)-2,2-dimethyl-1,3-dioxolane 

Relevant articles and documents

Deamination process of O-phenylenediamine mother liquor

The invention discloses a deamination process of O-phenylenediamine mother liquor, and belongs to the technical field of production of O-phenylenediamine. The deamination process comprises the following steps: firstly, heat exchange of the ortho-phenylenediamine mother liquor through a heat exchanger. After step two, nitrogen is introduced into the deamination tank 5 - 8min, a heat O-phenylenediamine mother liquor is added, the fan is opened, the nitrogen gas flow takes away ammonia gas, and the O-phenylenediamine mother liquor is discharged from the outlet of the mother liquor. Step II, Step I and Step II were repeated until the concentration ≤ 3g/L of ammonia in the ortho-phenylenediamine mother liquor was found to complete the deamination of o-phenylenediamine mother liquor. By the arrangement of the heat exchanger and the deamination tank, the O-phenylenediamine mother liquor can be deamination repeatedly, and the ammonia gas can be removed more fully and thoroughly under the action of ammonia gas and a fan.

Fluorine-containing polyfunctional (meth) acrylate composition low refractivity material and reflection reducing film

PCT No. PCT/JP97/01952 Sec. 371 Date Feb. 9, 1998 Sec. 102(e) Date Feb. 9, 1998 PCT Filed Jun. 9, 1997 PCT Pub. No. WO97/47585 PCT Pub. Date Dec. 18, 1997Fluorine-containing polyfunctional (meth)acrylate represented by the formula (1), as well as a composition, a low refractivity material and a reflection reducing film in which the (meth)acrylate is utilized: wherein X stands for a fluoroalkyl group of C1-14 having 3 or more F, or a fluorocycloalkyl group of C3-14 having 4 or more F; Y1, Y2, and Y3 stand for H, an acryloyl group or a methacryloyl group, and at least two of Y1, Y2, and Y3 stand for an acryloyl group or a methacryloyl group; Z stands for H or an alkyl group of C1-3; and n and m is an integer of 0 or 1, and n+m=1.

Highly selective synthesis of [(perfluoroalkyl)methyl]oxiranes (by the addition of iodoperfluoroalkanes to allyl acetate)

Mixtures of regioisomeric adducts of monoiodoperfluoroalkanes RF-I (RF = C4F9, C6F13, C8F17) with allyl acetate, RFCH2CHICH2OAc (1a-1c) and rearranged adducts RFCH2CH(OAc)-CH2I (2a-2c), were converted chemoselectively to the corresponding oxiranes RFCH2CH(-O-)CH2 (3a-3c) in yields of 94-96% (total yields of the two-step synthesis starting from RF-I were 85-87%). The chemoselectivity of the oxirane formation appeared to be very dependent on the solvent used. Dependence on the reaction conditions on formation of byproducts RFCH=CHCH2OAc (4a-4c) and RFCH=CHCH2OH (5a-5c) in the epoxidation reaction was studied.