38573-93-2

Basic information

• Product Name: [(1β,4β,7-syn)-Bicyclo[2.2.1]hept-2-en-7-yl]trimethylstannane
• Synonyms: [(1β,4β,7-syn)-Bicyclo[2.2.1]hept-2-en-7-yl]trimethylstannane
• CAS NO: 38573-93-2
• Molecular Formula: C10H18Sn
• Molecular Weight: 256.96
• Mol File: 38573-93-2.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: [(1β,4β,7-syn)-Bicyclo[2.2.1]hept-2-en-7-yl]trimethylstannane(CAS DataBase Reference)
• NIST Chemistry Reference: [(1β,4β,7-syn)-Bicyclo[2.2.1]hept-2-en-7-yl]trimethylstannane(38573-93-2)
• EPA Substance Registry System: [(1β,4β,7-syn)-Bicyclo[2.2.1]hept-2-en-7-yl]trimethylstannane(38573-93-2)

Safety Data

• Hazardous Substances Data: 38573-93-2(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 17946-71-3 (trimethylstannyl)lithium 
• 20047-65-8 syn-7-bromonorbornene 
• 38423-82-4 potassium trimethylstannate 
• 1066-45-1 trimethyltin(IV)chloride 
• 22365-94-2 anti-C₇H₉Br 
• 16643-09-7 trimethylstannyl sodium 
• 688-73-3 tri-n-butyl-tin hydride 
• 993-16-8 methyltin(IV) trichloride 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 
• 1631-73-8 trimethylstannane 

Relevant articles and documents

Nucleophilic substitution of bromonorbornenes and derivatives by electron transfer reactions

The photoinitiated substitution reactions of anti-7-bromobenzonorbornadiene (5), its syn isomer 6, exo-anti-13-bromobenzocyclobutanorbornene (7), syn-7-bromonorbornene (8) and bromonorbornane (9) with Me3Sn - and Ph2P- anions, in liquid ammonia, are here informed to occur with good yields of substitution. The stereochemical outcome is discussed in terms of calculations with the B3LYP functional and the 6-31+G* basis set; the solvent being included as a continuum through the PCM model. The experimental relative chemical reactivity of pairs of substrates toward a given anion is also presented.