38607-73-7Relevant academic research and scientific papers
THE REACTION OF 1,3,2-OXAZAPHOSPHOLIDINE-2-THIONES WITH GRIGNARD REAGENTS. A GENERAL SYNTHESIS OF CHIRAL PHOSPHINOTHIOIC ACID
Hall, C. Richard,Inch, Thomas D.
, p. 489 - 493 (2007/10/02)
With Grignard reagents 1,3,2-oxazaphospholidine-2-thiones derived from (-)-ephedrine and (+)-pseudoephedrine undergo P-O bond cleavage with retention of configuration at phosphorus and P-N bond cleavage with inversion of configuration.Both enantiomers of
