38644-98-3

Basic information

• Product Name: S-phenyl 2-(p-tolyl)ethanethioate
• Synonyms: S-phenyl 2-(p-tolyl)ethanethioate
• CAS NO: 38644-98-3
• Molecular Weight: 242.342
• Mol File: 38644-98-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: S-phenyl 2-(p-tolyl)ethanethioate(CAS DataBase Reference)
• NIST Chemistry Reference: S-phenyl 2-(p-tolyl)ethanethioate(38644-98-3)
• EPA Substance Registry System: S-phenyl 2-(p-tolyl)ethanethioate(38644-98-3)

Safety Data

• Hazardous Substances Data: 38644-98-3(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 35675-44-6 4-methylphenylacetyl chloride 
• 622-47-9 4-tolylacetic acid 

Relevant articles and documents

Fukuyama Cross-Coupling Approach to Isoprekinamycin: Discovery of the Highly Active and Bench-Stable Palladium Precatalyst POxAP

An efficient and user-friendly palladium(II) precatalyst, POxAP (post-oxidative-addition precatalyst), was identified for use in Fukuyama cross-coupling reactions. Suitable for storage under air, the POxAP precatalyst allowed reaction between thioesters and organozinc reagents with turnover numbers of ～90000. A series of 23 ketones were obtained with yields ranging from 53 to 99%. As proof of efficacy, an alternative approach was developed for the synthesis of a key precursor of the natural product isoprekinamycin.