38651-60-4

Upstream product

• 7785-26-4 (-)-α-pinene 
• 18881-04-4 (S)-cis-Verbenol 

Downstream Products

• 35107-41-6 (3R,4S)-4-Isopropenyl-3-methyl-cyclohexanone 
• 1093863-54-7 (-)-(1S,4S,5S)-4,6,6-trimethylbicyclo[3.1.1]heptan-2-one 2,4,6-triisopropylbenzenesulfonylhydrazone 
• 80-57-9 (+/-)-2,6,6-trimethylbicyclo[3.1.1]hept-2-en-4-one 
• 105497-89-0 (4R,5R)-4-Isopropyl-5-methyl-cyclohex-2-enone 
• 105497-90-3 (4R,5R)-5-methyl-4-(2-propyl)cyclohex-2-enone 
• 935670-67-0 (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol 
• 1292847-75-6 (2S,4S,4aR,8R,8aR)-3,4,4a,5,8,8a-hexahydro-4,7-dimethyl-2-phenyl-2H-chromene-4,8-diol 
• 473-55-2 trans-pinane 
• 28465-10-3 (+)-(1R)-cis-2,2-dimethyl-3-isopropenylcyclobutanemethanol acetate 
• 77510-81-7 (1R-cis)-(+)-2,2-dimethyl-3-(1-methylethenyl)cyclobutanemethanol acetate 

Relevant academic research and scientific papers

INTRODUCTION OF OXYGENATED FUNCTIONAL GROUPS INTO 3-CARENE AND 2-PINENE BY CULTURED CELLS

The biotransformation of the monoterpene hydrocarbons 3-carene and 2-pinene by cell suspension cultures of Nicotiana tabacum and Catharanthus roseus was investigated.The cultures have the ability to regio- and enantioselectively introduce the oxygenated functional groups into the C=C double bond and the allylic positions of the substrates. - Key words: Nicotiana tabacum; Solanaceae; Catharanthus roseus; Apocyanaceae; cultured cells; biotransformation; epoxidation; hydroxylation; carene; pinene.

Enantioselectivity in the Biotransformation of Mono- and Bicyclic Monoterpenoids with the Cultured Cells of Nicotiana tabacum

The biotransformation of the enantiomeric pairs of p-menthane and bicyclo and heptane derivatives with the cultured cells of Nicotiana tabacum was investigated.It was found that (i) the cultured cells discriminate the enantiomers of p-menthan-2-ol and bicycloheptan-2-ol and bicycloheptan-3-ol derivatives, and enantioselectively convert these alcohols to the corresponding ketones, (ii) the cells reduce the carbonyl group of p-methan-2-one derivatives to a high extent, but not that of p-menthan-3-ones, and (iii) the cells discriminate the enantiomers of bicyclohept-2-en-4-one (verbenone) and enantioselectively reduce the C-C double bond of the (1S,5S)-enantiomer.