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(1S,4R,5S)-4,6,6-trimethylbicyclo[3.1.1]heptan-2-one is a complex organic compound with a unique bicyclic structure. It is characterized by its molecular formula C??H??O and a molecular weight of 148.23 g/mol. (1S,4R,5S)-4,6,6-trimethylbicyclo[3.1.1]heptan-2-one features a ketone functional group at the 2-position, and three methyl groups at the 4, 6, and 6 positions, respectively. The stereochemistry is defined by the (1S,4R,5S) configuration, indicating the specific arrangement of atoms in three-dimensional space. It is an important intermediate in the synthesis of various natural products and pharmaceuticals, particularly in the production of pheromones and fragrances. The compound's physical properties, such as its melting point and solubility, can vary depending on the specific conditions and purity of the sample. Its chemical reactivity is influenced by the presence of the ketone group and the rigid bicyclic structure, which can participate in various types of chemical reactions, including reduction, oxidation, and substitution.

38651-60-4

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38651-60-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 38651-60-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,8,6,5 and 1 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 38651-60:
(7*3)+(6*8)+(5*6)+(4*5)+(3*1)+(2*6)+(1*0)=134
134 % 10 = 4
So 38651-60-4 is a valid CAS Registry Number.

38651-60-4Relevant academic research and scientific papers

INTRODUCTION OF OXYGENATED FUNCTIONAL GROUPS INTO 3-CARENE AND 2-PINENE BY CULTURED CELLS

Hirata, Toshifumi,Ikeda, Yoshihiro,Izumi, Shunsuke,Shimoda, Kei,Hamada, Hiroki,Kawamura, Toshinari

, p. 401 - 404 (1994)

The biotransformation of the monoterpene hydrocarbons 3-carene and 2-pinene by cell suspension cultures of Nicotiana tabacum and Catharanthus roseus was investigated.The cultures have the ability to regio- and enantioselectively introduce the oxygenated functional groups into the C=C double bond and the allylic positions of the substrates. - Key words: Nicotiana tabacum; Solanaceae; Catharanthus roseus; Apocyanaceae; cultured cells; biotransformation; epoxidation; hydroxylation; carene; pinene.

Enantioselectivity in the Biotransformation of Mono- and Bicyclic Monoterpenoids with the Cultured Cells of Nicotiana tabacum

Hamada, Hiroki

, p. 869 - 878 (2007/10/02)

The biotransformation of the enantiomeric pairs of p-menthane and bicyclo and heptane derivatives with the cultured cells of Nicotiana tabacum was investigated.It was found that (i) the cultured cells discriminate the enantiomers of p-menthan-2-ol and bicycloheptan-2-ol and bicycloheptan-3-ol derivatives, and enantioselectively convert these alcohols to the corresponding ketones, (ii) the cells reduce the carbonyl group of p-methan-2-one derivatives to a high extent, but not that of p-menthan-3-ones, and (iii) the cells discriminate the enantiomers of bicyclohept-2-en-4-one (verbenone) and enantioselectively reduce the C-C double bond of the (1S,5S)-enantiomer.

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