386768-45-2

Upstream product

• 55277-57-1 5-ethyl-5H-dibenzophosphole 5-oxide 
• 458570-20-2 (S_C)-7-carboxy-5-ethyl-3-(2-methylbutoxy)-5H-dibenzophosphole 5-oxide 
• 458570-19-9 (S_C)-7-cyano-5-ethyl-3-(2-methylbutoxy)-5H-dibenzophosphole 5-oxide 
• 458570-18-8 (S_C)-3-bromo-5-ethyl-7-(2-methylbutoxy)-5H-dibenzophosphole 5-oxide 
• 458570-15-5 3-bromo-5-ethyl-7-nitro-5H-dibenzophosphole 5-oxide 
• 458570-16-6 3-amino-7-bromo-5-ethyl-5H-dibenzophosphole 5-oxide 
• 458570-14-4 3-bromo-5-ethyl-5H-dibenzophosphole 5-oxide 
• 38261-81-3 (S)-2-methylbutyl tosylate 
• 386768-41-8 (S_C)-5-ethyl-3-(2-methylbutoxy)-7-(4-undec-10-enoxyphenoxycarbonyl)-5H-dibenzophosphole 5-oxide 
• 458570-17-7 3-bromo-5-ethyl-7-hydroxy-5H-dibenzophosphole 5-oxide 
• 121269-09-8 4-(undec-10-enoxy)anisole 
• 117721-44-5 p-hydroxyphenyl undec-10-en-1-yl ether 
• 16523-77-6 5-ethyl-5H-dibenzophosphole 
• 150-76-5 4-methoxy-phenol 

Relevant academic research and scientific papers

Enantiomeric resolution and determination of the absolute configuration of dibenzophosphole 5-oxides

The resolution of asymmetrically substituted dibenzophospholes via chromatographic separation of their cyclopalladium derivatives is described for the first time. The absolute configuration of the phosphorus atom was determined by X-ray crystallographic a

Synthesis of asymmetric dibenzophosphole 5-oxides: The first dibenzophosphole-based family of compounds with liquid crystalline behaviour

A synthesis of a new family of chiral dibenzophosphole 5-oxides is described. Using high-yield known reactions we report a method for the synthesis and optical resolution of chiral dibenzophospholes from an unsubstituted system. These molecules are the first examples of a new asymmetrically substituted dibenzophosphole-based group of systems with liquid crystal properties.

Asymmetric dibenzophospholes: New phosphorus-based chiral liquid crystals

(SP,SC)-5-Ethyl-3-(2-methylbutoxy)-7-(4-undec-10- enoxyphenoxycarbonyl)-5H-dibenzophosphole 5-oxide, the first example in the literature of a new asymmetrically substituted dibenzophosphole-based group of systems with liquid-crystal properties is described.