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• 523-27-3 9,10-Dibromoanthracene 
• 108-98-5 thiophenol 
• 602-60-8 9-nitroanthracene 
• 604-66-0 9,10-diacetoxyanthracene 

Relevant academic research and scientific papers

Organic electroluminescence devices based on anthracene sulfide derivatives

A series of anthracene derivatives are synthesized and fabricated as light-emitting materials in OLED devices. The incorporation of the chalcogen atoms, either oxygen or sulfur, in between the anthracene moiety and the alkyl or aryl substituents affected drastically the photo- and electroluminescence properties of the materials, especially the HOMO-LUMO band gap and the emitting color of the devices. The new anthracene sulfide derivatives represent a new design for further modification of other light-emitting doped materials.

Highly luminescent anthracene sulfides. Synthesis, experimental and DFT study of their optical properties and interaction with electron deficient nitroaromatic compounds

We report on the synthesis, thermal and photooxidative behavior and optical properties of a series alkyl and aryl sulfides with anthracene cores. All anthracene sulfides studied here were highly fluorescent. Their optical behavior was compared with that o

Synthesis of Di-, Tri-, and tetrasulfides through multifold carbon-sulfur cross-coupling reactions with indium tri(organothiolates) in a one-pot procedure

Pd-catalyzed multifold (2-, 3-, and 4-fold) carbon-sulfur cross-coupling reaction of indium tri(organothiolates) with polybromonated aromatic and heteroaromatic compounds was developed in a one-pot procedure. Both 2,5-dibromopyridine and 2,6-dibromopyridi

Mild persubstitution of di- and tetrabrominated arenes with arylthiolate nucleophiles

A mild selective protocol was used to prepare tetrakis(2-chlorophenylthio) anthracene from tetrabromoanthracene and sodium 2-chlorobenzenethiolate avoiding the thiolate self-attack. The uncatalyzed nucleophilic substitution of a series of mono-, di-, and tetrabrominated arenes by arylthiolate ions was attempted in mild conditions to investigate the scope of the substitution reaction regarding the size of the aromatic system as well as the number of bromine atoms. Successful reactions afforded only the persubstituted products in good purity and yield after a simple workup and chemoselectivity of Br versus Cl substituents was achieved for the tetrabromide.

Through-bond interaction between sulfonium and sulfenyl sulfur atoms having anthracene and naphthalene spacers

The reaction of 9-(methylsulfinyl)-10-(methylthio)anthracene with trifluoroacetic anhydride followed by quenching with aqueous NaHCO3 gives 9,9-bis(methylthio)-10-anthraquinone. The dithia dication and/or the corresponding carbodication via thr

The Reaction of 9-Bromoanthracene with Benzenethiolate Anion in Tetraglyme: Evidence against a Competing Electron-Transfer Mechanism

The reaction of 9-bromoanthracene (1) with benzenethiol(ate) in tetraglyme proceeds by a SNAr mechanism.The concurrent formation of anthracene is not due to a competing single-electron-transfer pathway involving either benzenethiol or benzenethiolate anion.

REACTIONS OF 9-NITROANTHRACENE WITH THIOLS IN LIQUID AMMONIA

Anthrylsulfides were obtained in high yields in the reaction of 9-nitroanthracene 1 with thiols.The reactions with thiolates resulted in the formation of aci-9,9'-dinitro-10,10'-dihydro-10,10'-bianthryl 2 via a 9-nitroanrthracene anion radical.