38704-87-9Relevant academic research and scientific papers
Sterically hindered nitrogen inversion in five-membered cyclic hydrazines
Usachev, Sergey V.,Nikiforov, Grygorii A.,Strelenko, Yurii A.,Belyakov, Pavel A.,Chervin, Ivan I.,Kostyanovsky, Remir G.
, p. 189 - 193 (2007/10/03)
We found that (PriNH)2 with MeCHO form only pyrazoline 1 because of the competitive crotonization of the latter followed by reaction with hydrazine; pyrazoline 2, pyrazolidinones 6 and 9, pyrazolidinol 8 and pyrazolidine 7, in which the inversion of nitrogen atoms is hindered by bulky PriN substituents, were prepared for the first time, and the inversion barriers were determined.
