38707-15-2

Upstream product

• 63316-04-1 methyl 4-oxo-1-phenyl-3-phosphorinanecarboxylate 
• 6775-11-7 bis(2-(carbomethoxy)ethyl)phenylphosphine 
• 23855-87-0 1-phenyl-4-phosphorinanone 

Downstream Products

• 39968-79-1 1,2,3,6-tetrahydro-1-phenyl-4-(1-pyrrolidinyl)phosphorin 1-oxide 
• 39968-78-0 4-(1-oxo-1-phenyl-1,2,3,6-tetrahydro-1λ⁵-phosphinin-4-yl)-morpholine 
• 49665-19-2 4,4-difluoro-1-phenyl-phosphinane 1-oxide 
• 39767-85-6 3,3-dibromo-1-oxo-1-phenyl-1λ⁵-phosphinan-4-one 
• 39767-69-6 8-phenyl-1,4-dioxa-8-phospha-spiro[4.5]decane 8-oxide 
• 7349-13-5 1-phenylphosphin-2,5-dien-4-one 1-oxide 
• 39968-81-5 (2-oxo-2,6-diphenyl-8-p-tolyl-1,2,3,4-tetrahydro-2λ⁵-isophosphinolin-5-yl)-p-tolyl-methanone 
• 39968-80-4 (2-oxo-2,6,8-triphenyl-1,2,3,4-tetrahydro-2λ⁵-isophosphinolin-5-yl)-phenyl-methanone 
• 39968-88-2 6-morpholin-4-yl-1-oxo-1-phenyl-1,2,7,8-tetrahydro-1λ⁵-phosphocine-4,5-dicarboxylic acid dimethyl ester 
• 39968-86-0 3,5-diphenyl-7a-pyrrolidin-1-yl-(3ar,7ac)-3a,4,5,6,7,7a-hexahydro-phosphinino[3,4-d]isoxazole 5ξ-oxide 
• 40930-26-5 1,3,5-triphenyl-4,5,6,7-tetrahydro-1H-phosphinino[4,3-c]pyrazole 5-oxide 
• 40930-27-6 1,6-dioxo-1-phenyl-1,2,5,6,7,8-hexahydro-1λ⁵-phosphocine-4,5-dicarboxylic acid dimethyl ester 
• 39968-82-6 2,6,8-triphenyl-1,2,3,4-tetrahydro-isophosphinoline 2-oxide 
• 39968-87-1 3,5-diphenyl-4,5,6,7-tetrahydro-phosphinino[3,4-d]isoxazole 5-oxide 

Relevant academic research and scientific papers

Desymmetrization Approach to the Synthesis of Optically Active P-Stereogenic Phosphin-2-en-4-ones

Two synthetic protocols for the conversion of 1-phenylphosphinan-4-ones to novel P-stereogenic 1-phenylphosphin-2-en-4-ones by enantioselective deprotonation followed by oxidation and by asymmetric organocatalytic halogenation accompanied by elimination have been developed. These two-step one-pot transformations provide convenient access to optically active 1-phenylphosphin-2-en-4-one 1-sulfide and 1-phenylphosphin-2-en-4-one 1-oxide of 96 and 55% enantiomeric purities, respectively.

Synthesis and structure of 6-exo-hydroxy-1,2-diphenyl-1-phosphoniatricyclo3,7>decane iodide, a derivative of 1-phosphaadamantane

The annelation reaction between 1,2,3,6-tetrahydro-1-phenyl-4-(1-pyrrolidinyl)phosphorin 1-oxide (10) and 2,2-bis(chloromethyl)acetophenone (7) leads to two stereoisomeric 7-benzoyl-3-phenyl-3-phosphabicyclononan-9-one 3-oxides 11a and 11b.Their di