38716-10-8Relevant articles and documents
Mild generation of 5-(2′-deoxyuridinyl)methyl radical from a phenyl selenide precursor
In, Seok Hong,Greenberg, Marc M.
, p. 5011 - 5013 (2007/10/03)
(Chemical Equation Presented) 5-(2′-Deoxyuridinyl)methyl radical (1) resulting from formal hydrogen atom abstraction from the methyl group of thymidine is produced from the respective phenyl selenide precursor (2) via 350 nm photolysis or mild thermolysis (37°C in the presence of glutathione) under aerobic or anaerobic conditions. The mild thermal generation of a nucleoside radical provides an alternative to previously reported photochemical methods, which are not always compatible with nucleic acids.
Radiation-induced binding of 2,2,6,6-tetramethyl-1,4-piperidone-N-oxyl to thymidine in oxygen-free aqueous solutions. Isolation and characterization of the adducts
Berger,Cadet,Ulrich
, p. 6 - 14 (2007/10/02)
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