38770-78-4Relevant academic research and scientific papers
142. Thermal rearrangements of halogen substituted aryl propargyl ethers
Sarcevic, Nada,Zsindely, Janos,Schmid, Hans
, p. 1457 - 1476 (1973)
7-Chloro-2-chloromethyl-benzofuran (13) and 3, 8-dichloro-2H-1-benzopyran (12) are the main products from the thermal rearrangement (230-260°) of 2, 6-dichlorophenyl propargyl ether (7). Compounds 17, 18 and 19 are also formed, but in much smaller amounts
Bimetal-Catalyzed Cascade Reaction for Efficient Synthesis of N-Isopropenyl 1,2,3-Triazoles via In-Situ Generated 2-Azidopropenes
Liu, Zhenhua,Hao, Wenjing,Liu, Zhixian,Gao, Wen,Zhang, Zhihai,Zhang, Yanan,Li, Xiang,Tong, Lili,Tang, Bo
supporting information, p. 2149 - 2154 (2019/06/13)
A bimetal-catalyzed cascade reaction for the synthesis of N-isopropenyl 1,2,3-triazoles in high yield is reported. This reaction involves the generation of 2-azidopropenes in situ by C(sp3)-OAr bond cleavage for click reaction and features a broad substrate scope, good functional group tolerance and readily available substrates.
