38793-75-8Relevant academic research and scientific papers
Diphenyl diselenide-assisted α-phenylthiolation of carbonyl compounds with diphenyl disulfide
Anbou, Hiroaki,Umeda, Rui,Nishiyama, Yutaka
experimental part, p. 1248 - 1250 (2012/01/31)
For the cesium carbonate-catalyzed α-phenylthiolation of carbonyl compounds with diphenyl disulfide, the yields of the α-phenylthio carbonyl compounds were dramatically improved by the addition of a catalytic amount of diphenyl diselenide.
Homologation of aldehydes using (phenylthiomethylene) triphenylarsorane: Selective preparation of α-thiophenoxyepoxides and phenylthioenol ethers
Boubia,Mioskowski,Manna,Falck
, p. 6023 - 6026 (2007/10/02)
The title arsonium ylide reacts with aldehydes to give exclusively α-thiophenoxyepoxides in THF and phenylthioenol ethers in THF/HMPA. The former adducts are readily transformed to α-thiophenoxy carbonyls and the latter to one-carbon homologated aldehydes.
ELIMINATIVE DEOXYGENATION OF SUBSTITUTED-α-HALOSULFOXIDES
Reutrakul, Vichai,Poochaivatananon, Patcharin
, p. 531 - 534 (2007/10/02)
The reaction of substituted-α-halosulfoxides with TiCl4-Zn in ether gave the corresponding phenyl vinyl sulfides in good yields.
