38795-60-7Relevant articles and documents
REARRANGEMENT OF RADICALS IN THE HOMOLYTIC ADDITION OF m-XYLENE TO METHYL METHACRYLATE
Galust'yan, G. G.
, p. 1065 - 1067 (2007/10/02)
Investigation of the products from the reaction of m-xylene with methyl methacrylate under the conditions of thermal and peroxide initiation led to the isolation and identification of compounds which indicated that rearrangement of the intermediate radical-adducts occured in addition to the main process.The rearrangement takes place mainly with 1,5-H migration, but 1,3-H migration also takes place at high temperatures (350 deg C).