3882-06-2Relevant articles and documents
Et4N[NO3(SnClPh3)2(SnPh 3NO3)]: A trinuclear organostannate complex and related derivatives
Diop, Tidiane,Diop, Libasse,Michaud, Francois,Ardisson, Jose Domingos
, p. 83 - 88 (2013/09/02)
Four new di- and triorganonitrato stannate complexes and related derivatives have been synthesized and characterized by infrared and Moessbauer spectroscopy. The structure of Et4N[NO 3(SnClPh3)2(SnPh3NO3)](1) has been determined by single-crystal X-ray diffraction analysis. In the trinuclear organostannate complex, each Sn IV atom is five-coordinated and adopts a trigonal-bipyramidal trans -OXSnC3(X = O or Cl) geometry. The overall coordination environment of the SnIV atoms is trans-octahedral for 2 and 3 or cis-trigonal-bipyramidal for 4. In the related derivatives, the NO3- anions behave as monodentate ligands.