3882-14-2

Usage

Uses

Used in Chemical Synthesis:
Monoallyl Phthalate is used as an intermediate in the production of diallyl phthalate (D416055), which is a reagent in ring-closing ruthenium based reactions. These reactions are crucial for the synthesis of complex organic molecules, making Monoallyl Phthalate an essential component in the chemical industry.
Used in Industrial Production:
As a by-product formed during the production of diallyl phthalate, Monoallyl Phthalate can be utilized in various industrial applications. Its presence in the production process highlights its potential for further development and use in different sectors, contributing to the efficiency and versatility of chemical manufacturing processes.

Upstream product

• 85-44-9 phthalic anhydride 
• 107-18-6 allyl alcohol 
• 182342-88-7 Phthalic acid 1-allyl ester 2-prop-2-ynyl ester 

Downstream Products

• 113793-40-1 o-((prop-2-enoxy)carbonyl)-α-diazoacetophenone 
• 182342-88-7 Phthalic acid 1-allyl ester 2-prop-2-ynyl ester 

Relevant academic research and scientific papers

Synthesis of New Dialkyl 2,2′-[Carbonyl bis (azanediyl)]dibenzoates via Curtius Rearrangement

The 2-(alkylcarbonyl)benzoic acids obtained by esterification of phthalic anhydride are converted into azide derivatives: alkyl 2-[(azidocarbonyl)amino]benzoates and to ureas: dialkyl 2,2′-[carbonyl bis (azanediyl)]dibenzoates. These transformations were carried out using classical Curtius rearrangement conditions in the presence of diphenylphosphoryl azide (DPPA) in a basic medium, followed by hydrolysis. Subsequently, a final condensation reaction of these urea derivatives enabled us to obtain, for the first time, the new alkyl derivatives, alkyl 2-[2,4-dioxo-1,2-dihydroquinazolin-3(4 H)-yl]benzoates. All the new compounds obtained in satisfactory yields were characterized by 1H and 13C NMR, and by X-ray crystallographic analysis.

Highly selective deprotection of tert-butyl esters using ytterbium triflate as a catalyst under mild conditions

Ytterbium triflate catalyses the deprotection of tert-butyl esters selectively in the presence of other esters under mild conditions in almost quantitative yields. The reactions are carried out in nitromethane (45°-50°C) using 5 mole percent of the catalyst.

Prop-2-ynyl as a protective group for carboxylic acids: A mild method for the highly selective deprotection of prop-2-ynyl esters using tetrathiomolybdate

It is shown that prop-2-ynyl esters are useful protecting groups for carboxylic acids and that they are selectively deprotected in the presence of other esters on treatment with tetrathiomolybdate under mild conditions.