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388567-20-2

[(1,10-phenanthroline)Pd(triethylsilyl)(NC(3,5-C6H3(CF3)2))][B(3,5-C6H3(CF3)2)4] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 388567-20-2 Structure

  • Basic information

    1. Product Name: [(1,10-phenanthroline)Pd(triethylsilyl)(NC(3,5-C6H3(CF3)2))][B(3,5-C6H3(CF3)2)4]
    2. Synonyms:
    3. CAS NO:388567-20-2
    4. Molecular Formula:
    5. Molecular Weight: 1504.24
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 388567-20-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [(1,10-phenanthroline)Pd(triethylsilyl)(NC(3,5-C6H3(CF3)2))][B(3,5-C6H3(CF3)2)4](CAS DataBase Reference)
    10. NIST Chemistry Reference: [(1,10-phenanthroline)Pd(triethylsilyl)(NC(3,5-C6H3(CF3)2))][B(3,5-C6H3(CF3)2)4](388567-20-2)
    11. EPA Substance Registry System: [(1,10-phenanthroline)Pd(triethylsilyl)(NC(3,5-C6H3(CF3)2))][B(3,5-C6H3(CF3)2)4](388567-20-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 388567-20-2(Hazardous Substances Data)

388567-20-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 388567-20-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,8,8,5,6 and 7 respectively; the second part has 2 digits, 2 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 388567-20:
(8*3)+(7*8)+(6*8)+(5*5)+(4*6)+(3*7)+(2*2)+(1*0)=202
202 % 10 = 2
So 388567-20-2 is a valid CAS Registry Number.

388567-20-2Downstream Products

388567-20-2Relevant articles and documents

Mechanism of palladium-catalyzed diene cyclization/hydrosilylation: Direct observation of intramolecular carbometalation

Perch, Nicholas S.,Widenhoefer, Ross A.

, p. 6332 - 6346 (2004)

The results of kinetic, deuterium-labeling, and low-temperature NMR studies have established a mechanism for the palladium-catalyzed cyclization/hydrosilylation of dimethyl diallylmalonate (1) with triethylsilane involving rapid, irreversible conversion of the palladium silyl complex [(phen)Pd(SiEt3)(NCAr)]+ [BAr4]- [Ar = 3,5-C6H3(CF3)2] (4b) and 1 to the palladium 5-hexenyl chelate complex {(phen)Pd[η1,η 2-CH(CH2SiEt3)CH2C(CO 2Me)2CH2CH=CH2]}+ [BAr4]- (5), followed by intramolecular carbometalation of 5 to form the palladium cyclopentylmethyl complex trans-{(phen)Pd[CH 2CHCH2C(CO2Me)2CH 2CHCH2SiEt3]-(NCAr)}+ [BAr 4]- (6), and associative silylation of 6 to release 3 and regenerate 4b.

Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex

Perch, Nicholas S.,Widenhoefer, Ross A.

, p. 5251 - 5253 (2008/10/08)

Warming a solution of {(phen)Pd[η1:η2-CH(CH2SiEt3) CH2C(CO2Me)2CH2CH= CH2]}+[BAr4]- (4) at -41 °C led to first-order decay (κ = (4.7 ± 0.3) × 10-4 M s-1, ΔG? = 17.1 ± 0.1 kcal mol-1) with formation of the palladium cyclopentylmethyl complex {(phen)Pd-[CH2 CHCH2CC(CO2Me)2CH2CHCH2 SiEt3](NC Ar)}+-[BAr4]- (5) in 96 ± 10% yield (1H NMR).

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