388602-40-2

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 388602-39-9 (2S,3S,4S)-(+)-1-benzyloxy-2,4-dimethyl-6-trimethylsilyl-5-hexyn-3-ol 
• 79027-28-4 (2S)-3-(benzyloxy)-2-methylpropanal 
• 375395-74-7 (S)-4-trimethylsilyl-3-butyn-2-yl mesylate 

Downstream Products

• 388602-41-3 [(1S,2S)-1-((S)-2-Benzyloxy-1-methyl-ethyl)-2-methyl-hex-5-en-3-ynyloxy]-tert-butyl-dimethyl-silane 
• 388602-42-4 (-)-1-benzyloxy-2,4-dimethyl-7-octene-5-yn-3-ol 
• 388602-44-6 (4R,5R)-5-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2,4-trimethyl-3-prop-2-en-(E)-ylidene-[1,2]oxasilolane 
• 388602-43-5 [(1S,2S)-1-((S)-2-Benzyloxy-1-methyl-ethyl)-2-methyl-hex-5-en-3-ynyloxy]-dimethyl-silane 

Relevant academic research and scientific papers

Coupling of alkynylTMS derivatives with vinylic iodides. An efficient route to 1,3-enynes and dienes

matrix presented CuCl-promoted coupling of alkynylTMS derivatives with vinyl iodides leads to 1,3-enynes in high yield. Enynes prepared from homopropargylic alcohols undergo intramolecular hydrosilylation and subsequent silyl cleavage with TBAF to afford