388602-50-4

Upstream product

• 388602-48-0 [(E)-(1S,2S)-1-((R)-2-Benzyloxy-1-methyl-ethyl)-2-methyl-dec-5-en-3-ynyloxy]-tert-butyl-dimethyl-silane 
• 388602-47-9 [(2R,3S,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-6-trimethylsilanyl-hex-5-ynyloxymethyl]-benzene 
• 388602-46-8 (2S,3R,4R)-(+)-1-benzyloxy-2,4-dimethyl-6-trimethylsilyl-5-hexyn-3-ol 
• 79027-28-4 (2S)-3-(benzyloxy)-2-methylpropanal 
• 16644-98-7 (E)-1-iodohexene 
• 15933-59-2 1,1,3,3-tetramethyldisilazane 
• 388602-49-1 (2S,3R,4R,7E)-(-)-1-benzyloxy-2,4-dimethyl-7-dodecen-5-yn-3-ol 

Downstream Products

• 388602-51-5 (4R,5R)-5-((R)-2-Benzyloxy-1-methyl-ethyl)-3-[(E)-hept-2-en-(E)-ylidene]-2,2,4-trimethyl-[1,2]oxasilolane 

Relevant academic research and scientific papers

Coupling of alkynylTMS derivatives with vinylic iodides. An efficient route to 1,3-enynes and dienes

matrix presented CuCl-promoted coupling of alkynylTMS derivatives with vinyl iodides leads to 1,3-enynes in high yield. Enynes prepared from homopropargylic alcohols undergo intramolecular hydrosilylation and subsequent silyl cleavage with TBAF to afford