38908-96-2Relevant academic research and scientific papers
Radical Ions, 71. Oxidative Sulfurization of Acetylenes to 1,2-Dithiete and 1,4-Dithiine Radical Cations
Bock, Hans,Rittmeyer, Peter,Stein, Udo
, p. 3766 - 3781 (2007/10/02)
In reaction mixtures of acetylenes RCCR (1) with R = H, CH3, C2H5, C3H7, C4H9, C(CH3)3, C6H5 and ClSSCl/AlCl3/H2CCl2 or S8/SbCl5/H2CCl2 at 250 K first 1,2-dithiete radical cations R2C2S2*+ (2a - g) and after warming to 300 K in addition 1,4-dit
